相关研究将要

摘要：马克斯普朗克研究所（Max Planck Institute）从空气传播的喷射云火山灰中得到重大的科学发现，氯自由基具有较强的冰白氯化学活性，

Science: 冰岛火山“喷射云”含有漂白氯自由基

2011-05-31 13:49 · pobee

摘要：冰岛火山口喷发一年以后，岛火极少量的山含氯自由基对大气化学属性可产生重大影响。

冰岛火山“喷射云”的大气位置

One year after the Eyjafjallajökull volcano in Iceland brought European air traffic to a standstill its ash plume revealed a surprising scientific finding: Researchers at the Max Planck Institute for Chemistry in Mainz found that the ash plume contained not only the common volcanic gas sulfur dioxide, but also free chlorine radicals. Chlorine radicals are extremely reactive and even small amounts can have a profound impact on local atmospheric chemistry. The findings, which will be published in "Geophysical Research Letters" give solid evidence of volcanic plume chlorine radical chemistry and allowed calculations of chlorine radical concentrations.

It has been known for some time that volcanic eruptions emit chlorine-containing gases, causing scientists to suspect that highly reactive chlorine radicals could also be present. However, sufficient experimental evidence proved elusive. That changed when researchers analyzed air collected in the ash cloud emitted by the Eyjafjallajökull volcano. During three special flights conducted by Lufthansa in spring 2010 using the CARIBIC atmospheric measurement container, researchers collected air samples which they brought back to their laboratory in Mainz for analysis. Among the compounds they looked for were hydrocarbons.

"Each volcano has its own character," says Angela Baker, lead author of the paper. "We found that hydrocarbon concentrations were up to 70% lower inside the Eyjafjallajökull ash cloud than outside. Reaction with chlorine radicals was the only realistic explanation for the hydrocarbon losses. And further investigation confirmed that free chlorine radicals were the cause." The scientists calculated concentrations of up to 66,000 chlorine atoms per cubic centimeter of air. While modest compared to concentrations of other gases, chlorine radicals are normally absent, and it does not take much of these very reactive atoms to have a noticeable impact on atmospheric chemistry.

Hydrocarbons like propane and butane can be found even in the cleanest and most remote parts of the lower atmosphere. Normally they are removed when they react with hydroxyl radicals, but they react many times faster with chlorine radicals. In doing so the chlorine reactions leave their specific "signature" on the mixture of hydrocarbons in the air. This signature can, in turn, be used to calculate how many chlorine radicals were present. The Max Planck scientists who calculated volcanic ash cloud chlorine radical concentrations for the first time anticipate that similar results will be found in plumes from other volcanoes, such as the currently erupting Grimsvötn. They also hope that their method will be used during future studies to identify and understand volcanic chlorine radical chemistry.

冰岛火山口喷发一年之后，自由氯自由基确实存在于火山灰中。喷射云此外，冰白氯氯自由基具有极强的岛火化学活性，马克斯普朗克Max Planck研究所从空气中传播的山含火山灰中得到重大的科学发现：火山灰不仅含有二氧化硫，还有游离氯自由基。有漂而且还有游离氯自由基，自由极少量对当地大气化学属性都能产生重大影响。喷射云还可以检测氯自由基浓度。冰白氯火山灰成分不仅有二氧化硫，岛火这一发现证明氯自由基存在并能检测它的浓度，这一发现表明，相关研究将要发表在Geophysical Research Letters杂志上。

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